题名：The mixed marriage of copper and carbon ring-g-C3N4 nanosheet: A visible-light-driven heterogeneous Fenton-like catalyst

来源：Applied Surface Science

发表年代：2019年

作者：Lingli Wang, Yu Zhu, Dan Yang, Lei Zhao, Hanming Ding*, Zhaohui Wang*

Abstract  Effective photogenerated charge separation and rapid Cu(II)/Cu(I) redox cycling is still challenging for photocatalytic reactions and copper-based Fenton-like process, respectively. Herein, a novel heterogeneous Fenton-like catalyst of copper incorporated carbon ring-g-C₃N₄ (Cu-C-CN) was prepared through a facile calcination method. The carbon ring could be intimately connected with g-C₃N₄ via sp2-hybridized Csingle bondN bonds to form an in-plane π-conjugated structure. The carbon ring spliced g-C₃N₄ (C-CN) can serve as an effective electron-hole separator owing to the varied electron affinity of two domains (e.g. carbon-ring and g-C₃N₄). The copper species were further introduced to the framework of g-C₃N₄ via the Cusingle bondN bonds to act as acceptors of conduction-electrons from g-C₃N₄ and H₂O₂ activators. Taking the photodegradation of methylene blue (MB) as a model reaction, the decomposition efficiency over Cu-C-CN is 5.5 times higher than that of pristine g-C3N4, and would nearly linearly increase with pH. The notable enhancement in photodegradation efficiency could be ascribed to the synergetic collaboration between photocatalysis process and Fenton-like process to generate abundant radical dotOH and e−. The Cu-C-CN catalyst shows high recycling stability with negligible Cu leaching due to the strong affinity of Cu²⁺ to g-C3N4 framework. The strategy of coupling Fenton-like catalysts, electron-deficient domains (e.g. carbon-ring) into semiconductor-based photocatalysis provides a facile and promising solution to the remediation of water pollution with solar energy.

The-mixed-marriage-of-copper-and-carbon-ringgC3N4-nanosheet-A-visiblelightdriven-heterogeneous-Fentonlike-catalystApplied-Surface-Science.pdf